Photoinitiators pis are used as catalyzers for inks and lacquers that are cured with ultraviolet uv light, and they can contaminate foodstuffs by mass transference. Irgacure 184 basf irgacure 500 basf irgacure 819 basf matting agents. In line with the jablonskitype diagram, the ground state of irgacure 907 excites to a higher state, which is characterized by singlet state s 2, followed by an internal conversion ic. Study of the migration of photoinitiators used in printed. With the cas registry number 947193, it is also named as methanone, 1hydroxycyclohexylphenyl. The aim of the present paper is to study the migration of six photoinitiators irgacure 184, benzophenone, irgacure 651, irgacure 907, itx, and eha into food simulants distilled water, 3% acetic acid wv in aqueous. Take our free online course to learn how to to properly apply and use your msds. Page 1 of 2 general irgacure 184 is a highly efficient nonyellowing photoinitiator which is used to initiate the photopolymerisation of chemically unsaturated prepolymers e.
Photoinitiator 184 is an efficient free radical type i nonyellowing photoinitiator for uv polymerization of monofunctional or multifunctional polyacrylate monomers and oligomers. Irgacure 184 by igm resins is a highly efficient, nonyellowing photoinitiator. It is widely used in printing varnishes, plastic coatings, wood coatings, adhesives, lithographic printing ink, screen printing ink, flexographic. Cn1283670c free radical polymerization method having. Low color liquid acylphosphine oxide photoinitiators. Photokinetic study of irgacure 784 dye in an epoxy resin photopolymer article pdf available in proceedings of spie the international society for optical engineering 7358 may 2009 with 712. The iupac name of this chemical is 1hydroxycyclohexylphenylmethanone. Opened drums should be closed after use to protect the product against light. Coating effects segment ciba irgacure 184 photoinitiator edition. Uv light has two important characteristics which are wavelength and intensity. Compound darocur 1173 irgacure 184 irgacure 2959 darocur mbf irgacure 651 structure spectrum 0. Products task risk assessments coshh assessments safety data sheets about us our story our team. Low color liquid acylphosphine oxide photoinitiators blends for uv coating applications e.
Photocrosslinkable polymers for biomedical applications 57 in order to obtain crosslinked polymers, it is necessary to generate free radicals in the system that will induce a free radical chain polymerization of monomers and oligomers. This is highly efficient non yellowing photoinitiator, which is used to initiate the photopolymerisation of chemically unsaturated prepolymers in combination with mono or multifunctional vinyl monomers 2. Utilizing highthroughput experimentation as a tool in the discovery process michael j. Strazisar, hermann bach, all bayer polymers, llc, pittsburgh, pennsylvania introduction in 2001 the concept of using a uva lamp to cure a primer system for the automotive refinish. The degree of risk is governed by the burning substance and the fire conditions. Irgacure 184, irgacure 127, irgacure 651, irgacure 907. Photocrosslinkable polymers for biomedical applications. Identification of unknown photoinitiators in offset uv. The formation of free radicals from irgacure 184 photoinitiator. Upon exposure to light, the sensitizer either forms free radicals directly, or is converted to an excited state before forming free radicals by abstracting a hydrogen atom from the monomer or solvent.
Also due to its unprecedented speed and nonyellowing properties, it is the best recommendation for thick film and white pigmented coating. The population analysis confirms that irgacure 907 prefers to undergo hemolytic photochemical cleavage to generate two free radical intermediates. Free radicals polymerization of urethane acrylate using photoinitiator. Solid photoinitiator for radical polymerisation of unsaturated resins after uv light exposure. Irgacure 2959 has the highest solubility among usual photoinitiators.
Irgacure 184 recommended use of the chemical and restriction on use recommended use. Formulation for cationic metal coatings component % function epoxy resin inert flexibilizer photoinitiator 6070 2030 dow uvr6160 polycaprolactone triol sulfonium salt e. The present invention discloses a method of polymerization by free radical polymerization mechanism, thereby forming a product and apparatus for this method. Irgacure 784 is sensitive to visible light and any exposure to sunlight should be avoided. Abs aluminum cold rolled steel glass hdpe pet pmma polycarbonate polypropylene pvc. Dsx 1514 basf tego viscoplus 3000 evonik tego chemie dsx 2000 basf tego viscoplus 3030 evonik tego chemie rheolate 288 elementis. Sigmaaldrich material safety data sheet date printed. Cas 947193 irgacure 184 1hydroxycyclohexyl phenyl ketone msds toxicity property.
Uv photopolymerization, using the photoinitiator 1hydroxycyclohexyl phenyl ketone irgacure 184, was used to polymerize the. Pdf the migration of photoinitiators from uvlacquered cardboards into the. Huguenard ciba specialty chemicals corporation, 540 white plains road, tarrytown ny 10530 usa ciba specialty chemicals inc. Irgacure 907 chemical information, properties, structures, articles, patents and more chemical data. When irgacure 784 is dissolved in a solvent or a formulation it is. Theoretical study on photochemistry of irgacure 907. Irgacure 184 safety data sheet download msds ghsclp. Safety data sheet rochester institute of technology. Industrial adhesives and sealants online materials database. A photoinitiator is a molecule that creates reactive species free radicals, cations or anions when exposed to radiation uv or visible. Irgacure 184 solid by oregon state firemarshal websi location pdf.
Especially suited for white pigmented formulations and for curing thick sections. It is used to initiate the photopolymerization of chemically unsaturated prepolymers like acrylates, in combination with mono or multifunctional vinyl monomers. Im currently working with 2 hydrogels using the photoinitiator irgacure 2959 i2959. Msds irgacure 184 1hydroxycyclohexyl phenyl ketone cas. It can be used alone or in combination with chivacure 184 or chivacure bdk. Study the material safety data sheets for the hazards of the chemical, learn the instructions on handling, storage and the emergency measures in case of accident take our free online course to learn how to to properly apply and use your msds complete a full risk assessment for your workplace so that you can map out all the hazards into a single comprehensive coshh assessment. Omnirad 184 former irgacure 184 by igm resins is a nonyellowing photoinitiator. Used to initiate the photopolymerization of chemically unsaturated prepolymers including acrylates in combination with mono or multifunctional vinyl monomers.
Pdf photokinetic study of irgacure 784 dye in an epoxy. Determination of photoinitiators in printing inks used in food contact materials. Pdf migration of photoinitiators from uvcuring inks on cardboards. A preliminary study on the effects of photoinitiator and.
The terms of this safety data sheet sds do not create or infer any. By substantially constant radiation for irradiating the polymerizable composition to be prepared by free radical polymerization mechanism, and the radiation pulse is substantially free. Its smooth creamy paper, a little yellowed by age, was of a kind that had not been manufactured for at least forty years past. Synthetic photoinitiators are key components in photopolymers i. Irgacure 184 usage photoinitiator 184 is an efficient free radical type i nonyellowing photoinitiator for uv polymerization of monofunctional or multifunctional polyacrylate monomers and oligomers. Composite with two different thicknesses have been. Furthermore, and due to its proven low furthermore, and due to its proven low cellular toxicity, this photoinitiator can also be employed in the photopolymerization of polymers and copolymers intended for biomedical and. He could guess, however, that the book was much older than that. The computed spin density difference showed that the unpaired electrons are located on the carbonyl carbon atom and the c. The lowintensity band at higher wavelenght 341 nm also disapears rapidly, which is clearly observed in spectrum recorded for more concentrated solution fig.
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